Product ID:CALCO UNLEADED GASOLINE
MSDS Date:10/03/1988
FSC:9130
NIIN:00-148-7103
MSDS Number: BGWLH

CHEVRON ENVIRONMENTAL HEALTH CENTER,INC.

15299 SAN PABLO AVE.
RICHMOND, CA 94804-0054
US

Emergency Phone: 415-233-3737

Info Phone: 415-233-3737

Cage: 0AHD1

CHEVRON ENVIRONMENTAL HEALTH CENTER INC

4054 RICHMOND, CA 94804 US

Telephone: 800-582-3835

Cage: 0AHD1

GASOLINE

CAS: 8006-61-9

RTECS: LX3300000

Fraction By Weight: TO 100%

OSHA PEL 300 PPM/500 STEL

ACGIH TLV: 300 PPM/500STEL;9192

BENZENE (SARA III)

CAS: 71-43-2

RTECS: CY1400000

Fraction By Weight: 1.2-1.4%

OSHA PEL 1PPM/5STEL;1910.1028

ACGIH TLV: 10 PPM; A2; 9192

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

TOLUENE (SARA III)

CAS: 108-88-3

RTECS: XS5250000

Fraction By Weight: 4.3-6.5%

OSHA PEL 200 PPM/150 STEL

ACGIH TLV: 50 PPM; 9293

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

XYLENES (O-,M-,P- ISOMERS) (SARA III)

CAS: 1330-20-7

RTECS: ZE2100000

Fraction By Weight: 5.1-7.7%

OSHA PEL 100 PPM/150 STEL

ACGIH TLV: 100 PPM/150STEL;9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

METHYL TERT-BUTYL ETHER (SARA III)

CAS: 1634-04-4

RTECS: KN5250000

Fraction By Weight: <10%

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

CYCLOHEXANE (SARA III)

CAS: 110-82-7

RTECS: GU6300000

Fraction By Weight: 0.5-2.4%

OSHA PEL 300 PPM

ACGIH TLV: 300 PPM, 9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

ETHYL BENZENE (SARA III)

CAS: 100-41-4

RTECS: DA0700000

Fraction By Weight: 1.2-1.4%

OSHA PEL 100 PPM/125 STEL

ACGIH TLV: 100 PPM/125STEL 9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

LD50 LC50 Mixture:ORAL RAT LD50 18,800 MG/KG
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:PRODUCT IS IRRITATING TO
EYE,SKIN,RESPIRATORY TRACT AND DEPRESSES THE CENTRAL NERVOUS
SYSTEM. CHRONIC OVER EXPOSURE MAY CAUSE LIVER,KIDNEY, OR CENTRAL
NERVOUS SYSTEM DAMAGE.
Explanation of Carcinogenicity:CONTAINS BENZENE;LISTED BY ALL THREE.
ALSO AN API STUDY FOUND LIVER CANCER IN MICE EXPOSED TO GASOLINE
VAPORS.
Effects of Overexposure:EYE/SKIN CONTACT:TRANSITORY IRRITATION.
INHALED:RESPIRATORY IRRITATION,CENTRAL NERVOUS SYSTEM DEPRESSION
INCLUDING,EUPHORIA,HEADACHE,DIZZINESS,DROWINESS,FATIGUE,TREMORS,CON
VULSIONS,NAUSEA,VOMITING,DIA RRHEA,LOSS OF CONSCIOUSNESS.AND
FINALLYDEATH. INGESTED:G/I IRRITATION,PLUS SYMPTOMS SIMILAR TO
THOSE UNDER "INHALED".
Medical Cond Aggravated by Exposure:PRE-EXISTING EYE,SKIN CONDITIONS OR
IMPAIRED LIVER,KIDNEY FUNCTION MAY BE AGGRAVATED BY THIS PRODUCT.

First Aid:EYE:FLUSH WITH WATER 15 MIN. SKIN:WASH WITH SOAP & WATER.
REMOVE CONTAMINATED CLOTHING;LAUNDER BEFORE REUSE. INHALED:REMOVE
TO FRESH AIR.RESUSCITATE OR GIVE OXYGEN AS NEEDED. GET MEDICAL
CARE. INGESTE D:GET IMMEDIATE MEDICAL ATTENTION. DO NOT INDUCE
VOMITING. IF VOMITING OCCURS,MINIMIZE ASPIRATION HAZARD.

Flash Point Method:PMCC
Flash Point:<-49F
Lower Limits:1.3
Upper Limits:7.6
Extinguishing Media:DRY CHEMICAL,CARBON DIOXIDE,FOAM,WATER FOG. WATER
MAY BE INEEFFECTIVE,AS,PRODUCT WILL FLOAT AND MAY SPREAD FIRE.
Fire Fighting Procedures:WEAR SELF CONTAINED BREATHING APPARATUS IN
ENCLOSED AREAS. WATER SPRAY MAY BE USED TO COOL FIRE EXPOSED
CONTAINERS.
Unusual Fire/Explosion Hazard:VAPORS ARE HEAVIER THAN AIR,ACCUMULATING
IN LOW AREAS,TRAVELING ALONG GROUND AND MAY FLASH BACK FROM DISTANT
IGNITION SOURCE.

Spill Release Procedures:ELIMINATE IGNITION SOURCES. ISOLATE AREA. USE
PROTECTIVE EQUIPMENT AS NECESSARY. STOP LEAK AND CONTAIN SPILL.
DIKE AS NEEDED TO KEEP SPILL FROM DRAINS,WATER WAYS ETC. WATER FOG
MAY BE USED TO REDUCE V APORS & PERSONAL HAZARD. REPORT SPILL PER
LAW.
Neutralizing Agent:NONE

Handling and Storage Precautions:STORE IN A COOL,DRY,ISOLATED,WELL
VENTILATED WATER AREA. KEEP IGNITION SOURCES AWAY. GROUND
CONTAINERS TO PREVENT STATIC DISCHARGE DURING TRANSFERS.
Other Precautions:FIRE AND EXPLOSION ARE THE ACUTE HAZARDS OF THIS
PRODUCT. TAKE EXTRAORDINARY STEPS TO PREVENT THEM.

Respiratory Protection:IF NEEDED,USE NIOSH/MSHSA RESPIRATOR WITH
ORGANIC VAPOR CARTRIDGE OR PREFERRABLY, POSITIVE PRESSURE AIR
SUPPLIED RESPIRATOR OR SELF CONTAINED BREATHING APPARATUS.
Ventilation:USE EXPLOSION PROOF VENTILATION EQUIPMENT TO MAINTAIN
EXPLOSURE BELOW PEL/TLV.
Protective Gloves:IMPERVIOUS RUBBER OR POLYMER.
Eye Protection:SAFETY GLASSES,OR SPLASH GOGGLES.
Other Protective Equipment:SAFETY SHOWER/EYE WASH. WORK CLOTHING AS
NEEDED TO PROTECT FROM PROLONGED/REPEATED CONTACT.
Work Hygienic Practices:USE GOOD CHEMICAL HYGIENE PRACTICE. AVOID
UNNECESSARY CONTACT. MINIMIZE ALL CONTACT.
Supplemental Safety and Health
MSDS NO. 1365 CPS 201153 REVISION 9

HCC:F1
Boiling Pt:=25.C, 77.F
B.P. Text:25-225C
Vapor Pres:5-15 PSI
Vapor Density:3.5 (AIR)
Spec Gravity:0.72 - 0.76
Solubility in Water:NEGLIGIBLE
Appearance and Odor:CLEAR,COLORLESS TO STRAW YELLOW LIQUID;GASOLINE
ODOR.
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS
Stability Condition to Avoid:HEAT,SPARKS AND OTHER IGNITION
SOURCES,VAPOR ACCUMULATIONS.
Hazardous Decomposition Products:CARBON DIOXIDE,CARBON MONOXIDE

Waste Disposal Methods:DISPOSE I/A/W FEDERAL,STATE,LOCAL REGULATIONS.
PRODUCT QUALIFYS AS IGNITABLE WASTE AND CANNOT BE LANDFILLED. IF
RECOVERY OR RECYCLE ARE UNACCEPTABLE, INCINERATION MAY BE
ACCEPTABLE DISPOSAL METHOD.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.